Advances in Carbohydrate Chemistry and Biochemistry 47 by R. Stuart Tipson and Derek Horton (Eds.)

By R. Stuart Tipson and Derek Horton (Eds.)

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Evans and V. L. Frampton, Curbohydr. , 59 (1977) 571 -574. (94) M. TomaSkoviC, Z. Cimerman, Z. Stefanac, E. Pretsch, and J. Bendl, Microchem. , 27 (1982) 372-379. (95) H. Vesala, Curbohydr. , 78 (1980) 53-59. -G. Ekstrom and A. Olin, Actu Chem. , Ser. A , 31 (1977) 838-844. -P. Morel and C. Lhermet, Can. J. , 63 (1985) 2639-2643. (98) A. P. G. Kieboom, H. M. A. Buurmans, L. K. van Leeuwen, and H. J. van Benschop, Red. Truv. Chim. Pays-Bus, 98 (1979) 393-394. STEPHEN J. 8 At 52". In methanol. 1, complexformation is negligible.

130) M. E. Daman and K. Dill, Curbohydr. Rex, 102 (1982)47-57. (131) K. Luthman, A. Claesson, L. Kenne, and I. Cdregh, Carbohydr. Rex. 170 (1987) 167-179. (132) P. -J. Pen& and A. S. Perlin, Curbohydr. , 168 (1987) 163- 179. (133) M. E. Tate, personal communication. 36 STEPHEN J. 1 M solution of lanthanum perchlorate. c. is more suitable for this purpose. Electrophoreticmobility is not strictly proportional to the extent of complex-formation; it depends also on the bulk and shape of the molecule, which influence ionic mobility.

J. D. Sherman and C. C. Chao, Proc. Znt. Zeolite Conf, 7th, Tokyo, (1986) 1025 - 1032. 0. Hiroyuki and 0. Masaji, Ger. Offen. 2,626,194 (1976); Chem. , 86 (1977) 74,846; H. Odawara, Y. Noguchi, and M. Ono, Jpn. Kokai 76, I 10,048 (1976); Chem. , 86 (1977) 73,066; R. W. Neuzil and J. W. S. Pat. 4,024,331 (1977); Chem. , 87 (1977) 184,896. 40 STEPHEN J. 161There are, however, between such predictions and the actual separations, some discrepancieswhich indicate that the retention on the column is also affected by geometric constraints imposed by pore geometries and by the position of the cation in the zeolite.

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